Essentials of Chemical Reaction Engineering by H. Scott Fogler

Author:H. Scott Fogler
Language: eng
Format: epub, pdf
Publisher: Pearson Education Limited (US titles)
Published: 2018-03-05T16:00:00+00:00

As with competitive inhibition, two additional reaction steps are added to the Michaelis–Menten kinetics for uncompetitive inhibition, as shown in Reaction Steps 4 and 5 in Figure 9-11.

Reaction Steps

Uncompetitive Pathway

Figure 9-11 Steps in uncompetitive enzyme inhibition.

Uncompetitive inhibition pathway

Starting with the equation for the rate of formation of product, Equation (9-34), and then applying the pseudo-steady-state hypothesis to the intermediate (I · E · S), we arrive at the rate law for uncompetitive inhibition

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